On November 5, 2021, Grollier, Kevin; Chefdeville, Emmanuel; De Zordo-Banliat, Arnaud; Pegot, Bruce; Dagousset, Guillaume; Magnier, Emmanuel; Billard, Thierry published an article.HPLC of Formula: 2567-29-5 The title of the article was Fe-mediated nucleophilic trifluoromethylselenolation of activated alkyl bromides via umpolung reactivity of trifluoromethyl tolueneselenosulfinate. And the article contained the following:
Trifluoromethyl tolueneselenosulfonate is a versatile reagent which can be reduced by iron powder to generate in situ trifluoromethylselenolate anion which can then react with alkyl bromide to form (trifluoromethyl)selanes RSeCF3 [R = Bn, CH2Bn, CH2C(O)Ph, etc.] through SN2 reaction. The experimental process involved the reaction of 4-(Bromomethyl)-1,1′-biphenyl(cas: 2567-29-5).HPLC of Formula: 2567-29-5
The Article related to trifluoromethyl selane preparation, alkyl bromide trifluoromethyl tolueneselenosulfinate trifluoromethylselenolation iron powder, General Organic Chemistry: Synthetic Methods and other aspects.HPLC of Formula: 2567-29-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary