Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides. 1575-37-7, formula is C6H7BrN2, Name is 4-Bromobenzene-1,2-diamine. Organic compounds having carbon bonded to bromine are called organic bromides. Computed Properties of 1575-37-7.
Liu, Fang;Ye, Zhi-Peng;Hu, Yuan-Zhuo;Gao, Jie;Zheng, Lan;Chen, Kai;Xiang, Hao-Yue;Chen, Xiao-Qing;Yang, Hua research published 《 N,N,N’,N’-Tetramethylethylenediamine-Enabled Photoredox-Catalyzed C-H Methylation of N-Heteroarenes》, the research content is summarized as follows. Aiming at the valuable methylation process, readily available and inexpensive N,N,N’,N’-tetramethylethylenediamine (TMEDA) was first identified as a new Me source in photoredox-catalyzed transformation in this work. By virtue of this simple methylating reagent, a facile and practical protocol for the direct C-H methylation of N-heteroarenes I (R = H, Cl, Me, F; R1 = H, F, Cl, Br, trifluoromethyl; RR1 = -(CH=CH-CH=CH)-; R2 = H, Me; R3 = Me, Bn, prop-2-en-1-yl, etc.), II (R4 = H, Me) and III (R5 = H, Br, ethynyl; R6 = H, Cl) was developed, featuring mild reaction conditions, broad substrate scope, and scalability. Mechanistic studies disclosed that a sequential photoredox, base-assisted proton shift, fragmentation, and tautomerization process was essentially involved.
1575-37-7, 4-Bromo-1,2-diaminobenzene can be obtained from 1,2-diaminobenzene via acetylation followed by bromination and alkaline hydrolysis.
4-Bromobenzene-1,2-diamine, also known as 4-Bromobenzene-1,2-diamine, is a useful research compound. Its molecular formula is C6H7BrN2 and its molecular weight is 187.04 g/mol. The purity is usually 95%.
4-Bromo-1,2-diaminobenzene is a dye that is used in diagnostic
procedures to detect the presence of amide groups. 4-Bromo-1,2-diaminobenzene can be used as an inhibitor for cationic polymerization reactions. It also has tuberculostatic activity and inhibits the growth of Mycobacterium tuberculosis. This compound reacts with aniline to form a benzimidazole derivative that contains a reactive amine group. The reaction between this amine group and different electrophiles generates benzimidazole compounds with different properties that are useful in nucleophilic attack reactions. The reaction between 4-bromo-1,2-diaminobenzene and methyl ethyl sulfide produces a luminescent probe that can be used to detect hydrogen bonds., Computed Properties of 1575-37-7
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary