Vinyl bromides undergo the Heck reaction, which involves C-C coupling with alkene to give substituted alkenes. 20469-65-2, formula is C8H9BrO2, Name is 1-Bromo-3,5-dimethoxybenzene. Methyl bromide is a precursor in the manufacture of several chemicals and is employed as a soil sterilant, mainly for seed production. Synthetic Route of 20469-65-2.
Hatch, Chad E.;Martin, Maxwell I.;Gilmartin, Philip H.;Xiong, Lu;Beam, Danielle J.;Yap, Glenn P. A.;Von Bargen, Matthew J.;Rosenthal, Joel;Chain, William J. research published 《 Electrochemically Mediated Oxidation of Sensitive Propargylic Benzylic Alcohols》, the research content is summarized as follows. The preparation and characterization of N-hydroxytetrafluorophthalimide (TFNHPI) and pseudo high throughput development of a green electrochem. oxidation protocol for sensitive propargylic benzylic alcs. RC6H4CH(OH)CC (R = H, 4-OMe, 2-Me, 3-Br, etc.), 1-(3,5-bis(trifluoromethyl)phenyl)-2-propyn-1-one, 1-(3,5-dimethoxyphenyl)-2-propyn-1-one, 1-(naphthalen-2-yl)-2-propyn-1-one that employs TFNHPI as a stable electrochem. mediator were described. The electrochem. oxidation of propargylic benzylic alcs. was leveraged to develop short synthetic pathways to prepare gram quantities of resveratrol natural products such as (±)-pauciflorol F and (±)-isopauciflorol F.
Synthetic Route of 20469-65-2, 1-Bromo-3,5-dimethoxybenzene, also known as 1-Bromo-3,5-dimethoxybenzene, is a useful research compound. Its molecular formula is C8H9BrO2 and its molecular weight is 217.06 g/mol. The purity is usually 95%.
1-Bromo-3,5-dimethoxybenzene is used as an intermediate in the synthetic preparation of pharmaceutical inhibitors via cross-coupling reactions.
1-Bromo-3,5-dimethoxybenzene can be synthesized by using 1,3-dimethoxybenzene via iridium-catalyzed arene borylation.
1-Bromo-3,5-dimethoxybenzene (1BDMB) is a synthetic molecule that can be used as an electron acceptor in organic photovoltaic cells. 1BDMB is a salt of the sodium salt of resorcylic acid and 1,3-dibromo-5,5-dimethoxybenzene. It has been shown to have a radical mechanism for the generation of free radicals. The radical mechanism is initiated by light absorption by the ruthenium complex at the center of the molecule which induces photoinduced electron transfer from the ruthenium to 1BDMB. This process results in electron transfer from the donor to an acceptor molecule, such as oxygen or nitrogen. The pharmacokinetic properties of this compound are not well known; however, it has been demonstrated that it can be synthesized through a cross-coupling reaction with other aromatic compounds such as stemofuran., 20469-65-2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary