In 2019,Journal of Solid State Chemistry included an article by Liu, Jian-Jun; Yu, Li-Mei; Han, Fu-Xu; Chen, Fu-Yu; Cheng, Fei-Xiang. Category: bromides-buliding-blocks. The article was titled 《A thioether-containing luminescent metal-organic framework for highly selective and sensitive detection of Ag(I) ion》. The information in the text is summarized as follows:
A stable three-dimensional coordination polymer, [Eu2(pbbp)(pbsd)3] (1) (H2pbsd = 2,2′-((1,4-phenylenebis(methylene))bis(sulfanediyl))dinicotinic acid, H2pbbp·2Cl = 1,1′-(1,4-phenylene-bis(methylene))-bis(3-carboxy pyridinium) dichloride), was prepared by the solvothermal reaction of Eu(NO3)3·6H2O, H2pbbp·2Cl and H2pbsd in mixed solvent of DMF and H2O, which was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy, and thermogravimetric analyses. 1 exhibits a 3D 6-connected sqcl network decorated by uncoordinated Lewis basic thioether groups. In particular, 1 shows excellent application as luminescent sensor for sensing Ag+ ions in ethylene glycol solution with high sensitivity and selectivity based on luminescence quenching effect. The experimental part of the paper was very detailed, including the reaction process of 1,4-Bis(bromomethyl)benzene(cas: 623-24-5Category: bromides-buliding-blocks)
1,4-Bis(bromomethyl)benzene(cas: 623-24-5) belongs to organobromine compounds.Depending on the type of carbon to which the bromine is bonded, organic bromide could be alkyl, alkenyl, alkynyl, or aryl. Due to the reactivity of bromide, they are used as potential precursors or important intermediates in organic synthesis. Category: bromides-buliding-blocks
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary