Jayaprakash, Harikrishnan published an article in 2021. The article was titled 《Mn(I) phosphine-amino-phosphinites: a highly modular class of pincer complexes for enantioselective transfer hydrogenation of aryl-alkyl ketones》, and you may find the article in Dalton Transactions.Name: Bromopentacarbonylmanganese(I) The information in the text is summarized as follows:
A series of Mn(I) catalysts with readily accessible and more π-accepting phosphine-amino-phosphinite (P'(O)N(H)P) pincer ligands have been explored for the asym. transfer hydrogenation of aryl-alkyl ketones which led to good to high enantioselectivities (up to 98%) compared to other reported Mn-based catalysts for such reactions. The easy tunability of the chiral backbone and the phosphine moieties makes P'(O)N(H)P an alternative ligand framework to the well-known PNP-type pincers.Bromopentacarbonylmanganese(I)(cas: 14516-54-2Name: Bromopentacarbonylmanganese(I)) was used in this study.
Bromopentacarbonylmanganese(I)(cas: 14516-54-2) has many other uses. It is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene and toluene) in the presence silver salt.Name: Bromopentacarbonylmanganese(I)
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary