Computed Properties of C9H11BrO3In 2021 ,《Tuning the Molecular Packing of Self-Assembled Amphiphilic PtII Complexes by Varying the Hydrophilic Side-Chain Length》 appeared in Chemistry – A European Journal. The author of the article were Herkert, Lorena; Selter, Philipp; Daniliuc, Constantin G.; Baeumer, Nils; Palakkal, Jasnamol P.; Fernandez, Gustavo; Hansen, Michael Ryan. The article conveys some information:
Understanding the relation between mol. design and packing modes constitutes one of the major challenges in self-assembly and is essential for the preparation of functional materials. Herein, the authors have achieved high precision control over the supramol. packing of amphiphilic PtII complexes by systematic variation of the hydrophilic side-chain length. A novel approach of general applicability based on complementary x-ray diffraction and solid-state NMR spectroscopy has allowed the authors to establish a clear correlation between mol. features and supramol. ordering. Systematically increasing the side-chain length gradually increases the steric demand and reduces the extent of aromatic interactions, thereby inducing a gradual shift in the mol. packing from parallel to a long-slipped organization. Notably, the authors’ findings highlight the necessity of advanced solid-state NMR techniques to gain structural information for supramol. systems where single-crystal growth is not possible. The authors’ work further demonstrates a new mol. design strategy to modulate aromatic interaction strengths and packing arrangements that could be useful for the engineering of functional materials based on PtII and aromatic mols. In the experiment, the researchers used many compounds, for example, 1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8Computed Properties of C9H11BrO3)
1-Bromo-3,4,5-trimethoxybenzene(cas: 2675-79-8) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.Computed Properties of C9H11BrO31-Bromo-3,4,5-trimethoxybenzene can be used to synthesize analogs of HA14-1, which shows promising anticancer properties.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary