《Applying Gewald reaction for the preparation of some novel aminothieno derivatives featuring noroxymorphone skeletal backbone》 was written by Bagherpour, Saeed; Mojtahedi, Mohammad M.; Abaee, M. Saeed. Application In Synthesis of (Bromomethyl)cyclopropane And the article was included in Journal of Sulfur Chemistry in 2020. The article conveys some information:
Synthesis of several novel semisynthetic aminothieno derivatives containing the noroxymorphone skeletal backbone using a one-pot Gewald reaction conditions was reported. The Gewald reaction conditions involved reaction of elemental sulfur and malononitrile under refluxing piperidine/ethanol. In the experimental materials used by the author, we found (Bromomethyl)cyclopropane(cas: 7051-34-5Application In Synthesis of (Bromomethyl)cyclopropane)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Application In Synthesis of (Bromomethyl)cyclopropane
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary