《Synthesis and Structure of Organyltriphenylphosphonium and Stibonium Hexabromoplatinates》 was written by Zykova, A. R.; Sharutin, V. V.; Sharutina, O. K.; Senchurin, V. S.. Related Products of 1530-32-1 And the article was included in Russian Journal of General Chemistry in 2020. The article conveys some information:
Organyltriphenylphosphonium and -stibonium hexabromoplatinates were synthesized by the reaction of potassium hexabromoplatinate with organyltriphenylphosphonium and -stibonium bromides in acetonitrile or water. The complexes [Ph3PC2H5]2[PtBr6] and [Ph3PCH2Ph]2[PtBr6] were obtained by recrystallization from DMSO; the complexes [Ph3PCH2Ph][PtBr5(Et2SO-S)] and [Ph4Sb·Et2SO-O]2[PtBr6], by recrystallization of benzyltriphenylphosphonium and tetraphenylstibonium hexabromoplatinates from di-Et sulfoxide. According to the x-ray data, phosphorus atoms in cations have a distorted tetrahedral coordination and antimony atoms, a distorted trigonal-bipyramidal coordination due caused by the Sb···O:SEt2 interaction. In the experiment, the researchers used Ethyltriphenylphosphonium bromide(cas: 1530-32-1Related Products of 1530-32-1)
Ethyltriphenylphosphonium bromide(cas: 1530-32-1) is a phase transfer catalyst, used to accelerate the cure of phenolic-based epoxy resins, certain fluoroelastomer resins and thermosetting powder coatings. CatOnium ETPB is also used as catalysts in the synthesis of certain organic compounds.Related Products of 1530-32-1
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary