Formula: C5BrMnO5In 2020 ,《In Situ Solution-State Characterization of MOF-Immobilized Transition-Metal Complexes by Infrared Spectroscopy》 was published in ACS Applied Materials & Interfaces. The article was written by Mamlouk, Hind; Elumalai, Palani; Kumar, Manyam Praveen; Aidoudi, Farida H.; Bengali, Ashfaq A.; Madrahimov, Sherzod T.. The article contains the following contents:
Transition metal catalysts immobilized on the surface of MOFs, are being utilized for an ever increasing number of reactions ranging from couplings to olefin oligomerization. While these reactions are usually performed in solution, unlike their homo-geneous counterparts, the insolubility of the MOF systems makes it difficult to obtain detailed mechanistic information by in situ spectroscopic anal. in solution In this report, we present a synthetic method to solubilize these systems by grafting oligomers on the surface of the MOF particles, making it possible to characterize these species by transmission IR spectros-copy. The fundamental photochem. of these catalysts was also studied and compared to that of their homogeneous counterparts. This work establishes a proof of principle for in solution monitoring of heterogeneous catalysts. In the part of experimental materials, we found many familiar compounds, such as Bromopentacarbonylmanganese(I)(cas: 14516-54-2Formula: C5BrMnO5)
Bromopentacarbonylmanganese(I)(cas: 14516-54-2) has many other uses. It is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene and toluene) in the presence silver salt.Formula: C5BrMnO5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary