Guo, Jiabao; Zhao, Yizhuo; Wang, Peng; Song, Yang; Shao, Yifei; Zhu, Li; Yao, Xiaoquan published the artcile< Copper loaded nitrogen-rich mesoporous carbon nitride as a highly efficient photocatalyst for selective oxidative cleavage of C(sp3)-C(sp3) bonds at room temperature under visible light>, Electric Literature of 401-78-5, the main research area is amide preparation green chem; amine photocatalytic oxidative cleavage copper mesoporous carbon nitride nanocatalyst.
Herein, a novel copper loaded nitrogen-rich mesoporous carbon nitride material was designed and synthesized, and utilized as a highly efficient photocatalyst for the inert C-C bond cleavage of amines such as N-phenylmorpholine, 1,4-diphenylpiperazine, tributylamine, etc. under blue light irradiation With oxygen as a benign oxidant, good to excellent yields were achieved for various functionalized amines at room temperature, even including sluggish aliphatic amines. The method may provide a cost-effective and environmentally friendly alternative for the direct oxidative cleavage of amines.
Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about Aromatic amides Role: SPN (Synthetic Preparation), PREP (Preparation). 401-78-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3, Electric Literature of 401-78-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary