HPLC of Formula: 17696-11-6In 2019 ,《Fenton-Inspired C-H Functionalization: Peroxide-Directed C-H Thioetherification》 was published in Journal of Organic Chemistry. The article was written by Groendyke, Brian J.; Modak, Atanu; Cook, Silas P.. The article contains the following contents:
Substoichiometric iron mediates the thioetherification of unactivated aliphatic C-H bonds directed by resident silylperoxides. Upon exposure to a catalytic amount of iron(II) triflate, TIPS-protected peroxides bearing primary, secondary, and tertiary C-H sites undergo chemoselective thioetherification of remote C-H bonds with diaryl disulfides. The reaction demonstrates a broad substrate scope and functional group tolerance without the use of any noble metal additives. Mechanistic experiments suggest that the reaction proceeds through 1,5-H atom abstraction by a hydroxyl radical generated with iron. The results came from multiple reactions, including the reaction of 8-Bromooctanoic acid(cas: 17696-11-6HPLC of Formula: 17696-11-6)
8-Bromooctanoic acid(cas: 17696-11-6) acid is used in the synthesis of 8-(N-Methyl-4,4′-bipyridinyl)- octanoic acid. 8-Mercaptooctanoic acid was prepared from 8-bromooctanoic acid. And 8-Bromooctanoic Acid is a useful compound for sonodynamic therapy.HPLC of Formula: 17696-11-6
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary