《Isomechanical Groups in Molecular Crystals and Role of Aromatic Interactions》 was written by Gabriele, Benjamin P. A.; Williams, Craig J.; Lauer, Matthias Eckhard; Derby, Brian; Cruz-Cabeza, Aurora J.. Application of 586-76-5 And the article was included in Crystal Growth & Design in 2020. The article conveys some information:
We have measured mech. properties in mol. crystals of a series of para-substituted benzoic acids using nanoindentation. Two linear correlations were found for these materials: first between the Young’s modulus and the m.p. per unit of volume, and second between the hardness and the crystal cohesive energy d. These correlations, however, were found to only hold within isomech. groups. These are groups of materials with similar interaction strengths and dimensionalities. A close anal. of the intermol. interactions present in these crystals revealed that structures with aromatic rings interacting through t-type interactions may achieve higher interaction dimensionalities and thus result in harder crystals than those with rings interacting through aromatic stacking. In these systems, thus, the dimensionality of the aromatic interactions in the crystals appears to play the major role in their mech. behavior. We correlate mech. properties measured in mol. crystals of a series of para-substituted benzoic acids, first with their m.p. per unit of volume and second with the crystals’ cohesive energy d. Structures with aromatic rings interacting through t-type interactions may achieve higher interaction dimensionalities and thus result in harder crystals than those with rings interacting through aromatic stacking. The experimental process involved the reaction of 4-Bromobenzoic acid(cas: 586-76-5Application of 586-76-5)
4-Bromobenzoic acid(cas: 586-76-5) has been used to study the metabolic fate of 2-,3-and 4-bromo benzoic acids in rat hepatocytes incubation using high temperature liquid chromatography. It was used in bromine-specific detection of the metabolites of 2-,3-and 4-bromobenzoic acid in the urine and bile of rats by inductively coupled plasma mass spectrometry.Application of 586-76-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary