《Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes》 was written by Fan, Pei; Lan, Yun; Zhang, Chang; Wang, Chuan. Recommanded Product: 1779-49-3 And the article was included in Journal of the American Chemical Society in 2020. The article conveys some information:
An unprecedented asym. acyl-carbamoylation of pendant alkenes tethered on aryl carbamic chlorides with both aliphatic and aromatic aldehydes has been developed via the cooperative catalysis of a chiral nickel-PHOX complex and tetrabutylammonium decatungstate. This reaction represents the first example of merging hydrogen-atom-transfer photochem. and asym. transition metal catalysis in difunctionalization of alkenes. Using this protocol, a variety of oxindoles bearing a challenging quaternary stereogenic center are furnished under mild conditions in highly enantioselective manner. In the experiment, the researchers used Methyltriphenylphosphonium bromide(cas: 1779-49-3Recommanded Product: 1779-49-3)
Methyltriphenylphosphonium bromide(cas: 1779-49-3) is a lipophilic molecule with a cation allowing for it to be used to deliver molecules to specific cell components. Also considered an antineoplastic agent.Recommanded Product: 1779-49-3
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary