Betori, Rick C.; May, Catherine M.; Scheidt, Karl A. published the artcile< Combined Photoredox/Enzymatic C-H Benzylic Hydroxylations>, HPLC of Formula: 2725-82-8, the main research area is photoredox chemoenzymic benzylic hydroxylation; C−H oxidation; chemoenzymatic catalysis; chiral alcohols; ketoreductase; photoredox catalysis.
Chem. transformations that install heteroatoms into C-H bonds are of significant interest because they streamline the construction of value-added small mols. Direct C-H oxyfunctionalization, or the one step conversion of a C-H bond to a C-O bond, could be a highly enabling transformation due to the prevalence of the resulting enantioenriched alcs. in pharmaceuticals and natural products,. Here we report a single-flask photoredox/enzymic process for direct C-H hydroxylation that proceeds with broad reactivity, chemoselectivity and enantioselectivity. This unified strategy advances general photoredox and enzymic catalysis synergy and enables chemoenzymic processes for powerful and selective oxidative transformations.
Angewandte Chemie, International Edition published new progress about Biochemical reaction kinetics. 2725-82-8 belongs to class bromides-buliding-blocks, and the molecular formula is C8H9Br, HPLC of Formula: 2725-82-8.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary