《Electrochemical Oxidation Enables Regioselective and Scalable α-C(sp3)-H Acyloxylation of Sulfides》 was written by Wang, Huamin; He, Meng; Li, Yongli; Zhang, Heng; Yang, Dali; Nagasaka, Masanari; Lv, Zongchao; Guan, Zhipeng; Cao, Yangmin; Gong, Fengping; Zhou, Zhilin; Zhu, Jingyun; Samanta, Supravat; Chowdhury, Abhishek Dutta; Lei, Aiwen. HPLC of Formula: 2623-87-2 And the article was included in Journal of the American Chemical Society in 2021. The article conveys some information:
A highly selective, environmentally friendly, and scalable electrochem. protocol for the construction of α-acyloxy sulfides e.g., (p-tolylthio)methyl acetate, through the synergistic effect of self-assembly-induced C(sp3)-H/O-H cross-coupling, is reported. It features exceptionally broad substrate scope, high regioselectivity, gram-scale synthesis, construction of complex mols. e.g., I, and applicability to a variety of nucleophiles such as acetic acid, cyclohexanecarboxylic acid, benzoic acid, benzotriazole, etc. Moreover, the soft X-ray absorption technique and a series of control experiments have been utilized to demonstrate the pivotal role of the self-assembly of the substrates, which indeed is responsible for the excellent compatibility and precise control of high regioselectivity in electrochem. protocol. The experimental process involved the reaction of 4-Bromobutanoic acid(cas: 2623-87-2HPLC of Formula: 2623-87-2)
4-Bromobutanoic acid(cas: 2623-87-2) belongs to carboxylic acids. The chief chemical characteristic of the carboxylic acids is their acidity. They are generally more acidic than other organic compounds containing hydroxyl groups but are generally weaker than the familiar mineral acids (e.g., hydrochloric acid, HCl, sulfuric acid, H2SO4, etc.).HPLC of Formula: 2623-87-2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary