Qiao, Lulin; Zhang, An-An; Chen, Jingchao; Li, Gao-Wei; Gao, Yuan-Yuan; Fan, Baomin; Liu, Lantao published the artcile< Palladium-catalyzed disilylation of 2-bromoarylferrocenes: An efficient approach to 1-Trimethylsilyl-2-(2-trimethylsilylaryl)ferrocenes>, Quality Control of 51605-97-1, the main research area is crystal structure mol disilylated ferrocene preparation; palladium catalyst disilylation bromoaryl ferrocene mechanism.
An unprecedented method for the palladium-catalyzed disilylation of 2-bromoarylferrocenes with hexamethyldisilane has been developed. The catalytic cycle is initiated by oxidative addition of 2-bromoarylferrocenes to Pd(0), followed by C-H activation to form a reactive five-membered C,C-palladacycle. By using this protocol, a variety of disilylated ferrocene compounds were obtained in moderate to good yields.
Tetrahedron Letters published new progress about C-H bond activation. 51605-97-1 belongs to class bromides-buliding-blocks, and the molecular formula is C9H12BrN, Quality Control of 51605-97-1.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary