The author of 《Ni-Catalyzed Reductive Liebeskind-Srogl Alkylation of Heterocycles》 were Ma, Yuanhong; Cammarata, Jose; Cornella, Josep. And the article was published in Journal of the American Chemical Society in 2019. Recommanded Product: 7051-34-5 The author mentioned the following in the article:
Herein we present a Ni-catalyzed alkylation of C-SMe with alkyl bromides for the decoration of heterocyclic frameworks I (R = H, 6-CN, 5-CF3, 2-thienyl, etc.; R1 = cyclohexyl, cyclobutyl, 4-pyranyl, etc.). The protocol, reminiscent to the Liebeskind-Srogl coupling, makes use of simple C(sp2)-SMe to be engaged in a reductive coupling. The reaction is suitable for a preponderance of highly valuable heterocyclic motifs. In addition to cyclic bromides, noncyclic alkyl bromides are well accommodated with exquisite levels of retention over isomerization. The protocol is scalable and permits orthogonal couplings in the presence of other functionalization handles. After reading the article, we found that the author used (Bromomethyl)cyclopropane(cas: 7051-34-5Recommanded Product: 7051-34-5)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Recommanded Product: 7051-34-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary