Li, Yanrong; Rajasree, Sreehari Surendran; Lee, Ga Young; Yu, Jierui; Tang, Jian-Hong; Ni, Ruidong; Li, Guigen; Houk, Kendall. N.; Deria, Pravas; Stang, Peter J. published an article in 2021. The article was titled 《Anthracene-triphenylamine-based platinum(II) metallacages as synthetic light-harvesting assembly》, and you may find the article in Journal of the American Chemical Society.Application In Synthesis of Tris(4-bromophenyl)amine The information in the text is summarized as follows:
Two trigonal prismatic metallacages 1 and 2 bearing triphenylamine and anthracene moieties are designed and synthesized to fabricate artificial light-harvesting systems (LHSs). These two cages are prepared via the coordination-driven self-assembly of two anthracene-triphenylamine-based tripyridyl ligand 3, three dicarboxylates, and six 90° Pt(II) acceptors. The design of the anthracene-triphenylamine chromophore makes possible the tunable excited-state property (like the emissive transition energy and lifetime) as a function of the solvent polarity, temperature, and concentration The synergistic photophys. footprint of these metallacages, defined by their high absorptivity and emission quantum yield (QY) relative to the free ligand 3, signifies them as a superior light sensitizer component in an LHS. In the presence of the fluorescent dye Nile Red (NR) as an energy acceptor, the metallacages display efficient (>93%) excited energy transfer to NR through an apparent static quenching mechanism in viscous DMSO solvent. After reading the article, we found that the author used Tris(4-bromophenyl)amine(cas: 4316-58-9Application In Synthesis of Tris(4-bromophenyl)amine)
In general, Tris(4-bromophenyl)amine(cas: 4316-58-9) is often used in the synthesis of porous luminescent covalent–organic polymers (COPs)Application In Synthesis of Tris(4-bromophenyl)amine
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary