Ding, Chao; Ren, Yaoyu; Sun, Caocao; Long, Jiao; Yin, Guoyin published their research in Journal of the American Chemical Society in 2021. The article was titled 《Regio- and Stereoselective Alkylboration of Endocyclic Olefins Enabled by Nickel Catalysis》.Related Products of 7051-34-5 The article contains the following contents:
Whereas there is a significant interest in the rapid construction of diversely substituted saturated heterocycles, direct and modular access is currently limited to the mono-, 2,3-, or 3,4-substitution pattern. This Communication describes the straightforward and modular construction of 2,4-substituted saturated heterocycles from readily available materials in a highly stereo- and regioselective manner, which sets the stage for numerous readily accessible drug motifs. The strategy relies on chain walking catalysis. In the experiment, the researchers used many compounds, for example, (Bromomethyl)cyclopropane(cas: 7051-34-5Related Products of 7051-34-5)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Related Products of 7051-34-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary