Merad, Jeremy; Grant, Phillip S.; Stopka, Tobias; Sabbatani, Juliette; Meyrelles, Ricardo; Preinfalk, Alexander; Matyasovsky, Jan; Maryasin, Boris; Gonzalez, Leticia; Maulide, Nuno published an article in 2022. The article was titled 《Direct stereodivergent olefination of carbonyl compounds with sulfur ylides》, and you may find the article in Journal of the American Chemical Society.Application of 5437-45-6 The information in the text is summarized as follows:
The reactivity of phosphorus and sulfur ylides towards carbonyl compounds constitutes a well-known dichotomy: the former gives olefins, while the latter gives epoxides. Herein, a stereodivergent carbonyl olefination which challenges this dichotomy, showcasing thiuronium ylides as valuable olefination reagents is presented. With this method, aldehydes are converted to Z-alkenes with high stereoselectivity and broad substrate scope, while N-tosylimines provide a similarly proficient entry to E-alkenes. In-depth computational and exptl. studies clarified the mechanistic details of this unusual reactivity. In addition to this study using Benzyl 2-bromoacetate, there are many other studies that have used Benzyl 2-bromoacetate(cas: 5437-45-6Application of 5437-45-6) was used in this study.
Benzyl 2-bromoacetate(cas: 5437-45-6) belongs to benzyl acetate. Benzyl acetate is a synthetic chemical produced for industry from benzyl alcohol and acetic acid, but is also naturally present in the essential oils of many plants, including jasmine and ylang ylang.Application of 5437-45-6
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary