《A Copper(I)-Catalyzed Radical-Relay Reaction Enabling the Intermolecular 1,2-Alkylborylation of Unactivated Olefins》 was written by Akiyama, Sota; Oyama, Natsuki; Endo, Tsubura; Kubota, Koji; Ito, Hajime. Name: Ethylbromofluoroacetate And the article was included in Journal of the American Chemical Society on April 7 ,2021. The article conveys some information:
The 1st catalytic intermol. 1,2-alkylborylation reaction via a radical-relay mechanism between unactivated olefins, bis(pinacolato)diboron, and an alkyl electrophile is reported. Successful implementation of this method requires that the competing boryl substitution of the alkyl electrophile is retarded to facilitate the radical relay. This challenge was overcome using electronically or sterically demanding alkyl electrophiles, which results in the simultaneous and highly regioselective introduction of a gem-difluoro, monofluoro, tertiary, or secondary alkyl group and a boryl group across the C:C double bond.Ethylbromofluoroacetate(cas: 401-55-8Name: Ethylbromofluoroacetate) was used in this study.
Ethylbromofluoroacetate(cas: 401-55-8) is a member of organofluorine compounds. Organofluorine compounds, which have carbon-fluorine bonds, show unique features such as high thermal and chemical stability, high surface activity, no light-absorbing ability, high pharmacological effect, and so on. Owing to their specific characters, they are indispensable chemicals for industry and our daily lives.Name: Ethylbromofluoroacetate
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary