Jayasundara, Chathurika R. K.; Gil-Negrete, Jose M.; Montero Bastidas, Jose R.; Chhabra, Arzoo; Martinez, M. Montserrat; Perez Sestelo, Jose; Smith, Milton R. III; Maleczka, Robert E. Jr. published the artcile< Merging Iridium-Catalyzed C-H Borylations with Palladium-Catalyzed Cross-Couplings Using Triorganoindium Reagents>, Electric Literature of 401-78-5, the main research area is aryl halide iridium catalyzed borylation palladium cross coupling organoindium; borylated alkynyl heteroaryl arene preparation; organoindium palladium catalyzed cross coupling boryl arene.
A versatile and efficient method to prepare borylated arenes furnished with alkyl, alkenyl, alkynyl, aryl and heteroaryl functional groups is developed by merging Ir-catalyzed C-H borylations (CHB) with a chemoselective Pd-catalyzed cross-coupling of triorganoindium reagents (Sarandeses-Sestelo coupling) with aryl halides bearing a boronic ester substituent. Using triorganoindium cross-coupling reactions to introduce unsaturated moieties enables the synthesis of borylated arenes that would be difficult to access through the direct application of the CHB methodol. The sequential double catalyzed procedure can be also performed in one vessel.
Journal of Organic Chemistry published new progress about Aryl halides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 401-78-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3, Electric Literature of 401-78-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary