《A highly stable amino-coordinated MOF for unprecedented block off N2 adsorption and extraordinary CO2/N2 separation》 was written by Zhang, Ling; Jiang, Ke; Jiang, Mengdie; Yue, Dan; Wan, Yating; Xing, Huabin; Yang, Yu; Cui, Yuanjing; Chen, Banglin; Qian, Guodong. Synthetic Route of C6H5Br2NThis research focused onzinc aminophenylenediacrylate coordination polymer preparation gas adsorption; crystal structure zinc aminophenylenediacrylate coordination polymer. The article conveys some information:
A highly stable amino-coordinated metal-organic framework ZJU-198 from (2E,2E0)-3,30-(5-amino-1,3-phenylene) diacrylic acid, was synthesized and structurally characterized, exhibiting high CO2 uptake of 105.8 cm3 cm-3 while blocking off N2 adsorption at 1.0 bar and 298 K, attributed to the unique pore window sizes. In addition to this study using 3,5-Dibromoaniline, there are many other studies that have used 3,5-Dibromoaniline(cas: 626-40-4Synthetic Route of C6H5Br2N) was used in this study.
3,5-Dibromoaniline(cas: 626-40-4) belongs to anime. Amines characteristically form salts with acids; a hydrogen ion, H+, adds to the nitrogen. With the strong mineral acids (e.g., H2SO4, HNO3, and HCl), the reaction is vigorous. Salt formation is instantly reversed by strong bases such as NaOH. Neutral electrophiles (compounds attracted to regions of negative charge) also react with amines; alkyl halides (R′X) and analogous alkylating agents are important examples of electrophilic reagents.Synthetic Route of C6H5Br2N
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary