Safety of (Bromomethyl)cyclopropaneIn 2019 ,《Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides》 was published in Chemical Communications (Cambridge, United Kingdom). The article was written by Yu, Weijie; Chen, Long; Tao, Jiasi; Wang, Tao; Fu, Junkai. The article contains the following contents:
A novel reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides was realized via photoredox/nickel dual catalysis to produce vinyl arene derivatives bearing all-carbon quaternary centers with excellent E-selectivity. A stoichiometric metal reductant was avoided by employing com. available N,N,N’,N’-tetramethylethylenediamine (TMEDA) as the terminal reductant. In the experiment, the researchers used many compounds, for example, (Bromomethyl)cyclopropane(cas: 7051-34-5Safety of (Bromomethyl)cyclopropane)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Safety of (Bromomethyl)cyclopropane
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary