《Palladium(II)-Catalyzed C-H Bond Arylation of Electron-Deficient Arenes at Room Temperature》 was published in Angewandte Chemie, International Edition in 2011. These research results belong to Tredwell, Matthew J.; Gulias, Moises; Gaunt Bremeyer, Nadine; Johansson, Carin C. C.; Collins, Beatrice S. L.; Gaunt, Matthew J.. Computed Properties of C6H4BBrF3K The article mentions the following:
Herein, we report that the C-H bond arylation of benzaldimines with aryl-BF3K salts can be catalyzed by Pd(OAc)2 at room temperature The mild reaction conditions enable the functionalization of substrates displaying sensitive functionality. E.g., arylation of (E)-benzaldimine I with PhBF3K gave 82% II. Benzaldimine I could be phenylated to II in good yield using benzene as a source of the aryl group. The results came from multiple reactions, including the reaction of potassium (3-bromophenyl)trifluoroborate(cas: 374564-34-8Computed Properties of C6H4BBrF3K)
potassium (3-bromophenyl)trifluoroborate(cas: 374564-34-8) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Computed Properties of C6H4BBrF3K
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary