《Transition metal- and light-free radical borylation of alkyl bromides and iodides using silane》 was written by Sun, Beiqi; Zheng, Sihan; Mo, Fanyang. Recommanded Product: 7051-34-5This research focused ontransition metal light free radical borylation alkyl bromide iodide; crystal structure mol structure optimized boronic ester alkyl preparation; radical borylation alkyl bromide iodide silane mechanism DFT. The article conveys some information:
We report operationally simple and neutral conditions for borylation of alkyl bromides and iodides to alkyl boronic esters under transition metal- and light-free conditions. A series of substrates with a wide range of functional groups were effectively transformed into the borylation products in moderate to good yields. Mechanistic studies, including radical clock experiments and DFT calculations, gave detailed insight into the radical borylation process. In the experiment, the researchers used many compounds, for example, (Bromomethyl)cyclopropane(cas: 7051-34-5Recommanded Product: 7051-34-5)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Recommanded Product: 7051-34-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary