《Practical and regioselective halo-trifluoromethylthiolation of sulfur ylides》 was written by Qin, Hongmei; Jia, Yimin; Wang, Na; Jiang, Zhong-Xing; Yang, Zhigang. Product Details of 5437-45-6 And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020. The article conveys some information:
A H2O mediated practical and highly regioselective chloro- and bromo-trifluoromethylthiolation of sulfur ylides was reported using a difunctionalization strategy. In the reaction sequence, sulfur ylides presumably reacted with an electrophilic trifluoromethylthiolating reagent to generate an α-SCF3 substituted sulfonium salt intermediate, which then underwent a substitution with nucleophilic halogens. After reading the article, we found that the author used Benzyl 2-bromoacetate(cas: 5437-45-6Product Details of 5437-45-6)
Benzyl 2-bromoacetate(cas: 5437-45-6) has been used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid.Product Details of 5437-45-6
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary