In 2022,Patel, Kaushalendra; Lanke, Veeranjaneyulu; Marek, Ilan published an article in Journal of the American Chemical Society. The title of the article was 《Stereospecific Construction of Quaternary Carbon Stereocenters from Quaternary Carbon Stereocenters》.Application of 7051-34-5 The author mentioned the following in the article:
Organoaluminum species promote a smooth nucleophilic substitution at quaternary C stereocenter of stereodefined polysubstituted cyclopropyl Me phosphate with a complete inversion of configuration, even when more reactive functional groups are present. The regio- and diastereoselectivity of the substitution is attributed to the existence of a bicyclobutonium intermediate. In the experimental materials used by the author, we found (Bromomethyl)cyclopropane(cas: 7051-34-5Application of 7051-34-5)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Application of 7051-34-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary