Palomino-Ruiz, Lucia; Rodriguez-Gonzalez, Sandra; Fallaque, Joel G.; Marquez, Irene R.; Agrait, Nicolas; Diaz, Cristina; Leary, Edmund; Cuerva, Juan M.; Campana, Araceli G.; Martin, Fernando; Millan, Alba; Gonzalez, M. Teresa published their research in Angewandte Chemie, International Edition in 2021. The article was titled 《Single-Molecule Conductance of 1,4-Azaborine Derivatives as Models of BN-doped PAHs》.Name: 9,10-Dibromoanthracene The article contains the following contents:
The single-mol. conductance of a series of BN-acene-like derivatives has been measured by using scanning tunneling break-junction techniques. A strategic design of the target mols. has allowed us to include azaborine units in positions that unambiguously ensure electron transport through both heteroatoms, which is relevant for the development of customized BN-doped nanographenes. We show that the conductance of the anthracene azaborine derivative is comparable to that of the pristine all-carbon anthracene compound Notably, this heteroatom substitution has also allowed us to perform similar measurements on the corresponding pentacene-like compound, which is found to have a similar conductance, thus evidencing that B-N doping could also be used to stabilize and characterize larger acenes for mol. electronics applications. Our conclusions are supported by state-of-the-art transport calculations In the part of experimental materials, we found many familiar compounds, such as 9,10-Dibromoanthracene(cas: 523-27-3Name: 9,10-Dibromoanthracene)
9,10-Dibromoanthracene(cas: 523-27-3) can be sublimated and oxidized to generate anthraquinone. Soluble in hot benzene and hot toluene, slightly soluble in alcohol, ether and cold benzene, insoluble in water.Name: 9,10-Dibromoanthracene
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary