Kopf, Sara; Neumann, Helfried; Beller, Matthias published their research in Chemical Communications (Cambridge, United Kingdom) in 2021. The article was titled 《Manganese-catalyzed selective C-H activation and deuteration by means of a catalytic transient directing group strategy》.Name: Bromopentacarbonylmanganese(I) The article contains the following contents:
A novel manganese-catalyzed C-H activation methodol. for selective hydrogen isotope exchange of benzaldehydes was presented. Using D2O as a cheap and convenient source of deuterium, the reaction proceeded with excellent functional group tolerance. High ortho-selectivity was achieved in the presence of catalytic amounts of specific amines, which in situ form a transient directing group. The results came from multiple reactions, including the reaction of Bromopentacarbonylmanganese(I)(cas: 14516-54-2Name: Bromopentacarbonylmanganese(I))
Bromopentacarbonylmanganese(I)(cas: 14516-54-2) has many other uses. It is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene and toluene) in the presence silver salt.Name: Bromopentacarbonylmanganese(I)
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary