Name: (Bromomethyl)cyclopropaneIn 2019 ,《Carbonylative C-C Bond Activation of Electron-Poor Cyclopropanes: Rhodium-Catalyzed (3+1+2) Cycloadditions of Cyclopropylamides》 was published in Angewandte Chemie, International Edition. The article was written by Dalling, Andrew G.; Yamauchi, Takayuki; McCreanor, Niall G.; Cox, Lydia; Bower, John F.. The article contains the following contents:
Rh-catalyzed carbonylative C-C bond activation of cyclopropylamides generates configurationally stable rhodacyclopentanones that engage tethered alkenes in (3+1+2) cycloadditions These studies provide the first examples of multicomponent cycloadditions that proceed through C-C bond activation of “”simple”” electron poor cyclopropanes. In the experiment, the researchers used many compounds, for example, (Bromomethyl)cyclopropane(cas: 7051-34-5Name: (Bromomethyl)cyclopropane)
(Bromomethyl)cyclopropane(cas: 7051-34-5) is used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.Name: (Bromomethyl)cyclopropane
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary