Burde, Ameya S.; Chemler, Sherry R. published the artcile< Copper-Catalyzed Enantioselective Oxysulfenylation of Alkenols: Synthesis of Arylthiomethyl-Substituted Cyclic Ethers>, Safety of Methyl 2-bromo-4-methoxybenzoate, the main research area is alkenol disulfide copper catalyst regioselective enantioselective oxysulfenylation; phenylthiomethyl cyclic ether preparation.
A complementary approach via copper catalysis was presented. This exoselective method provides enantioenriched arylthiomethyl-substituted tetrahydrofurans, phthalans, isochromans, and morpholines from acyclic alkenols. This method provides the largest scope to date for the exocyclization mode, and with generally high enantioselectivity. The enantioselectivity of this copper-catalyzed oxysulfenylation is rationalized by a proposed mechanism involving alkene oxycupration followed by C-S bond formation via radical-mediated atom transfer.
ACS Catalysis published new progress about Alkenyl alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 17100-65-1 belongs to class bromides-buliding-blocks, and the molecular formula is C9H9BrO3, Safety of Methyl 2-bromo-4-methoxybenzoate.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary