The author of 《Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes》 were Bergmann, Allison M.; Dorn, Stanna K.; Smith, Kevin B.; Logan, Kaitlyn M.; Brown, M. Kevin. And the article was published in Angewandte Chemie, International Edition in 2019. Product Details of 402-43-7 The author mentioned the following in the article:
Two methods are reported for the 1,2- and 1,1-arylboration of α-Me vinyl arenes. In the case of 1,2-arylboration, the formation of a quaternary center occurred through a rare cross-coupling reaction of a tertiary organometallic complex. 1,1-Arylboration was enabled by catalyst optimization and occurred through a β-hydride elimination/reinsertion cascade. Enantioselective variants of both processes are presented as well as mechanistic investigations.1-Bromo-4-(trifluoromethyl)benzene(cas: 402-43-7Product Details of 402-43-7) was used in this study.
1-Bromo-4-(trifluoromethyl)benzene(cas: 402-43-7) belongs to organobromine compounds.The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. Product Details of 402-43-7 Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary