Shintani, Ryo; Otomo, Haruka; Ota, Kensuke; Hayashi, Tamio published the artcile< Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C-H Bond Functionalization>, HPLC of Formula: 135999-16-5, the main research area is palladium catalyzed asym carbon hydrogen bond activation silylaryl triflate; dibenzosilole silicon stereogenic preparation; crystal structure dibenzosilole silicon stereogenic; mol structure dibenzosilole silicon stereogenic.
A Pd-catalyzed asym. synthesis of Si-stereogenic dibenzosiloles, e.g., 4-methoxy-5-tert-butyl-5-phenyl-5H-dibenzosilole, is developed through enantioselective C-H bond functionalization of prochiral 2-(arylsilyl)aryl triflates. High chemo- and enantioselectivities are achieved by employing a Josiphos-type ligand under mild conditions.
Journal of the American Chemical Society published new progress about Bidentate ligands Role: CAT (Catalyst Use), USES (Uses). 135999-16-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H7BrO2, HPLC of Formula: 135999-16-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary