Liu, Deyang; Zhang, Zelong; Yu, Jiang; Chen, Haihong; Lin, Xuan; Li, Ming; Wen, Lirong; Guo, Weisi published the artcile< Site-selective electrochemical thiocyanation of benzylic C-H bonds>, Safety of 1-Bromo-3-ethylbenzene, the main research area is alkylarene trimethylsilyl isothiocyanate electrochem regioselective thiocyanation; aralkyl thiocyanate preparation.
An electrochem. protocol for site-selective benzylic C(sp3)-H thiocyanation under mild reaction conditions was reported. The reaction demonstrated broad substrate scope and unique benzylic C-H site selectivity (2° > 3° > 1°) over the existing methods. Preliminary mechanistic studies indicated that the reaction probably underwent a radical-polar crossover process. This method was also successfully used for follow-up transformation and late-stage thiocyanation of bioactive mols.
Organic Chemistry Frontiers published new progress about Alkylarenes Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 2725-82-8 belongs to class bromides-buliding-blocks, and the molecular formula is C8H9Br, Safety of 1-Bromo-3-ethylbenzene.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary