Li, Hengchao; Chen, Hang; Zhou, Yang; Huang, Jin; Yi, Jundan; Zhao, Hongcai; Wang, Wei; Jing, Linhai published the artcile< Selective Synthesis of Z-Cinnamyl Ethers and Cinnamyl Alcohols through Visible Light-Promoted Photocatalytic E to Z Isomerization>, Recommanded Product: 2-Bromo-4-(trifluoromethyl)phenol, the main research area is cinnamyl ether alc diastereoselective photoisomerization iridium catalyst; allylic alcohols; cinnamyl ethers; iridium; isomerization; photocatalysis.
A photocatalytic E to Z isomerization of alkenes using an iridium photosensitizer under mild reaction conditions is disclosed. This method provides scalable and efficient access to Z-cinnamyl ethers and allylic alcs. in high yields with excellent stereoselectivity. Importantly, this method also provides a powerful strategy for the selective synthesis of Z-magnolol and honokiol derivatives possessing potential biol. activity.
Chemistry – An Asian Journal published new progress about Allyl ethers Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 81107-97-3 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3O, Recommanded Product: 2-Bromo-4-(trifluoromethyl)phenol.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary