Jensen, Kim L.; Poulsen, Pernille H.; Donslund, Bjarke S.; Morana, Fabio; Joergensen, Karl Anker published the artcile< Asymmetric Synthesis of γ-Nitroesters by an Organocatalytic One-Pot Strategy>, Reference of 3893-18-3, the main research area is unsaturated aldehyde nitroalkane diphenyltrimethylsilyloxymethylpyrrolidine enantioselective Michael addition oxidative esterification; gamma arylnitroester Baclofen piperidone stereoselective preparation; enantioselective Michael addition oxidative esterification catalyst diphenyl trimethylsilyloxymethyl pyrrolidine.
An enantioselective synthesis of γ-nitroesters by a one-pot asym. Michael addition/oxidative esterification of α,β-unsaturated aldehydes is presented. The procedure is based on merging the enantioselective organocatalytic nitroalkane addition with an N-bromosuccinimide-based oxidation The γ-nitroesters are obtained in good yields and enantioselectivities, and the method provides an attractive entry to optically active γ-aminoesters, 2-piperidones, and 2-pyrrolidones.
Organic Letters published new progress about Alkanes, nitro Role: RCT (Reactant), RACT (Reactant or Reagent). 3893-18-3 belongs to class bromides-buliding-blocks, and the molecular formula is C9H7BrO, Reference of 3893-18-3.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary