The author of 《A three-component difunctionalization of N-alkenyl amides via organophotoredox radical-polar crossover》 were Dhungana, Roshan K.; Granados, Albert; Sharique, Mohammed; Majhi, Jadab; Molander, Gary A.. And the article was published in Chemical Communications (Cambridge, United Kingdom) in 2022. Application of 401-55-8 The author mentioned the following in the article:
Herein, a three-component organophotoredox coupling of N-alkenyl amides I [R1 = Me, R2 = H, Me; R1R2 = (CH2)3, (CH2)5; R3 = H, Me] with α-bromocarbonyls II (R4 = F, Me; R5 = EtO, Et2N) and various nucleophiles NuH (Nu = OH, 4-ClC6H4S, 2-pyrimidinylthio, EtO, N3, etc.) to give the corresponding compounds III is reported. This transition metal-free difunctionalization protocol installs sequential C-C and C-Y (Y = S/O/N) bonds in alkenes. This reaction works with terminal and internal alkenes containing both cyclic and acyclic amides via radical-polar crossover. In the experiment, the researchers used many compounds, for example, Ethylbromofluoroacetate(cas: 401-55-8Application of 401-55-8)
Ethylbromofluoroacetate(cas: 401-55-8) is a member of organofluorine compounds. Organofluorine compounds, which have carbon-fluorine bonds, show unique features such as high thermal and chemical stability, high surface activity, no light-absorbing ability, high pharmacological effect, and so on. Owing to their specific characters, they are indispensable chemicals for industry and our daily lives.Application of 401-55-8
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary