Ahmad, Maha; Gaumont, Annie-Claude; Durandetti, Muriel; Maddaluno, Jacques published the artcile< Direct Syn Addition of Two Silicon Atoms to a CC Triple Bond by Si-Si Bond Activation: Access to Reactive Disilylated Olefins>, Related Products of 81107-97-3, the main research area is syn addition silicon carbon triple bond activation disilylated olefin; stereoselective disilylated heterocycle preparation; crystal structure mol silylalkenyl silicon oxygen heterocycle preparation; cyclization; disilane; heterocycles; palladium; vinylsilane.
A catalytic intramol. silapalladation of alkynes affords, in good yields and stereoselectively, syn-disilylated heterocycles of different chem. structure and size. When applied to silylethers, this reaction leads to vinylic silanols that undergo a rhodium-catalyzed addition to activated olefins, providing the oxa-Heck or oxa-Michael products, depending on the reaction conditions.
Angewandte Chemie, International Edition published new progress about Addition reaction, stereoselective. 81107-97-3 belongs to class bromides-buliding-blocks, and the molecular formula is C7H4BrF3O, Related Products of 81107-97-3.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary