Sun, Bin; Huang, Panyi; Yan, Zhiyang; Shi, Xiayue; Tang, Xiaoli; Yang, Jin; Jin, Can published the artcile< Self-Catalyzed Phototandem Perfluoroalkylation/Cyclization of Unactivated Alkenes: Synthesis of Perfluoroalkyl-Substituted Quinazolinones>, Product Details of C7H6BrNO2, the main research area is alkenyl quinazolinone perfluoroalkanesulfinate regioselective phototandem perfluoroalkylation cyclization; dihydrocyclicquinazolinonyl trifluoroalkane preparation.
A novel visible-light-induced radical tandem trifluoromethylation/cyclization of unactivated alkenes with sodium perfluoroalkanesulfinates (Rf = CF3, C3F7, C4F9, C6F13, C8F17) under air atm. was developed. A range of quinazolinones containing unactivated alkene moiety and sodium perfluoroalkanesulfinates were compatible with this transformation, leaded to a variety of perfluoroalkyl-substituted quinazoline alkaloids. Remarkably, the experiment was carried out without any metal catalyst, strong oxidant, or external photosensitizer.
Organic Letters published new progress about Alkenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 20776-50-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H6BrNO2, Product Details of C7H6BrNO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary