Hong, Bor-Cherng; Lin, Cheng-Wei; Liao, Wei-Kai; Lee, Gene-Hsiang published the artcile< Sequential Asymmetric Catalysis in Michael-Michael-Michael-Aldol Reactions: Merging Organocatalysis with Photoredox Catalysis in a One-Pot Enantioselective Synthesis of Highly Functionalized Decalines Bearing a Quaternary Carbon Stereocenter>, HPLC of Formula: 3893-18-3, the main research area is enantioselective synthesis decalin Michael Michael aldol organocatalyst photochem.
An expedited method has been developed for the enantioselective synthesis of highly functionalized decaline systems (e.g., I) containing seven contiguous stereogenic centers with high enantioselectivities (>99% ee). The one-pot methodol. comprises a cascade of organocatalytic double Michael-photocatalyzed Michael-aldol reactions of Et 2-bromo-6-formylhex-2-enoate, β-alkyl-α,β-unsaturated aldehydes, and α-alkyl-α,β-unsaturated aldehydes. The structure and absolute configuration of an appropriate product were confirmed by X-ray anal.
Organic Letters published new progress about Aldol addition. 3893-18-3 belongs to class bromides-buliding-blocks, and the molecular formula is C9H7BrO, HPLC of Formula: 3893-18-3.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary