Xiao, Yuting; Tian, Guohui; Li, Wei; Xie, Ying; Jiang, Baojiang; Tian, Chungui; Zhao, Dongyuan; Fu, Honggang published the artcile< Molecule Self-Assembly Synthesis of Porous Few-Layer Carbon Nitride for Highly Efficient Photoredox Catalysis>, Name: 4-Bromobenzylamine, the main research area is self assembly porous carbon nitride efficient photoredox catalysis.
Polymeric C nitride (C3N4) has emerged as the most promising candidate for metal-free photocatalysts but is plagued by low activity due to the poor quantum efficiency and low sp. surface area. Exfoliation of bulk crystals into ultrathin nanosheets proved to be an effective and widely used strategy for enabling high photocatalytic performances; however, this process is complicated, time-consuming, and costly. Here, the authors report a simple bottom-up method to synthesize porous few-layer C3N4, which involves mol. self-assembly into layered precursors, alc. mols. intercalation, and subsequent thermal-induced exfoliation and polycondensation. The as-prepared few-layer C3N4 expose more active sites and greatly enhance the separation of charge carriers, thus exhibiting a 26-fold higher hydrogen evolution activity than bulk counterpart. Also, both the high activity and selectivity for the oxidative coupling of amines to imines can be obtained under visible light that surpass those of other metal-free photocatalysts so far.
Journal of the American Chemical Society published new progress about Amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Name: 4-Bromobenzylamine.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary