Strekalova, Sofia; Kononov, Alexander; Rizvanov, Ildar; Budnikova, Yulia published the artcile< Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C-H amidation reactions>, Formula: C9H11Br, the main research area is acetamide preparation; benzene benzonitrile acetonitrile carbon hydrogen amidation copper catalyst electrochem.
A mild, efficient electrochem. approach to the site-selective direct C-H amidation of benzene and its derivatives with acetonitrile and benzonitrile to form amides RNC(O)R1 [R = Ph, 2-BrC6H4, Bn, etc.; R1 = Me, Ph] was developed. It has been shown that joint electrochem. oxidation of various arenes in the presence of a copper salt as a catalyst and nitriles leads to the formation of N-phenylacetamide from benzene and N-benzylacetamides from benzyl derivatives (up to 78% yield). A favorable feature of the process was mild conditions (room temperature, ambient pressure, no strong oxidants) that meet the criteria of green chem.
RSC Advances published new progress about Acetamides Role: SPN (Synthetic Preparation), PREP (Preparation). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Formula: C9H11Br.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary