Mao, Wenhui; Zhao, He; Zhang, Min published the artcile< Hydride transfer-initiated synthesis of 3-functionalized quinolines by deconstruction of isoquinoline derivatives>, Category: bromides-buliding-blocks, the main research area is aminomethyl phenyl quinoline preparation; isoquinolinium halide amino benzaldehyde hydride transfer initiated deconstruction.
Under transition metal catalyst-free conditions,presented a hydride transfer-initiated construction of novel 3-(2-aminomethyl)aryl quinolines from N-isoquinolinium salts and 2-aminobenzaldehydes, proceeding with the merits of operational simplicity, high step and atom efficiency, good substrate and functional group compatibility, and mild conditions. The products were formed by reacting with the isoquinolyl motif as a two-carbon synthon along with the cleavage of its C3-N bond. Given the interesting applications of 3-aryl quinolines, the developed chem. was anticipated to be further applied to develop new functional products.
Chemical Communications (Cambridge, United Kingdom) published new progress about Amino aldehydes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (aryl). 29124-57-0 belongs to class bromides-buliding-blocks, and the molecular formula is C7H6BrNO, Category: bromides-buliding-blocks.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary