MacNeil, Connor S.; Hsiang, Shou-Jen; Hayes, Paul G. published the artcile< Reversible dehydrogenation of a primary aryl borane>, Application In Synthesis of 576-83-0, the main research area is mesitylborane cleavage boron hydrogen bond phosphiniminepyrrolyl rhodium pincer complex; crystal structure phosphiniminepyrrolyl rhodium aminoborylene pincer complex; mol structure phosphiniminepyrrolyl rhodium aminoborylene pincer complex.
The consecutive activation of B-H bonds in mesitylborane (H2BMes; Mes = 2,4,6-Me3C6H2) by a 16-electron Rh(I) monocarbonyl complex, (iPrNNN)Rh(CO) (1-CO; iPrNNN = 2,5-[iPr2P:N(4-iPrC6H4)]2N(C4H2)-) is described. Dehydrogenative extrusion of the {BMes} fragment gave (iPrNNN)(CO)RhBMes (1-BMes). Addition of H2 gas to 1-BMes regenerated 1-CO and H2BMes, highlighting the ability of 1-CO to facilitate interconversion of {BMes} with dihydrogen. Reactivity studies revealed that 1-BMes promotes formal group transfer and that {BAr} fragments accessed by dehydrogenation are reactive entities.
Chemical Communications (Cambridge, United Kingdom) published new progress about Bond cleavage (boron-hydrogen). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Application In Synthesis of 576-83-0.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary