Luo, Xiaoyan; Zhou, Zhiqiang; Li, Xin; Liang, Xinmiao; Ye, Jinxing published the artcile< Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes>, Reference of 3893-18-3, the main research area is enantioselective organocatalytic phospha Michael alpha beta unsaturated aldehyde; diaryl phosphine oxide phospha Michael alpha beta unsaturated aldehyde; diphenyl trimethylsilyloxy pyrrolidine catalyzed phospha Michael unsaturated aldehyde; crystal mol structure bromophenyl diphenylphosphoryl propanol.
The enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes with diaryl phosphine oxides is explored for the first time using (S)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine as a catalyst. It afforded 1,4-addition adducts in good to excellent yields with up to 99% ee.
RSC Advances published new progress about Addition reaction (1,4-addition reaction). 3893-18-3 belongs to class bromides-buliding-blocks, and the molecular formula is C9H7BrO, Reference of 3893-18-3.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary