Liu, Xixi; Wang, Yanxin; Li, Bo; Liu, Bing; Wang, Wei; Xiang, Nian; Zhang, Zehui published the artcile< Catalytic dehydrogenation of amines to imines and the in-situ reduction of sulfoxides into sulfides>, Related Products of 3959-07-7, the main research area is nickel nitrogen doped carbon catalytic dehydrogenation amine sulfoxide.
The catalytic acceptorless dehydrogenation of primary amines into imines and H2 represents one of the most important organic transformations, and the in-situ utilization of the generated H2 for chem. reduction reactions has never been reported in previous research. Herein, nitrogen-doped carbon supported nickel catalysts (abbreviated as Ni/NC-T, where T represents the pyrolysis temperature) were facilely prepared by the simple pyrolysis process, and the Ni/NC-600 catalyst demonstrated excellent catalytic performance towards the tandem reaction of the dehydrogenation of primary amines into imines and the subsequent hydrodeoxygenation of sulfoxides into sulfides using the in-situ released H2, affording high to quant. yields. The developed methods demonstrated some advantages such as the use of heterogeneous non-noble metal catalysts with low cost and high stability, and the in-situ utilization of generated H2 with high atom efficiency.
Journal of Catalysis published new progress about Adsorption (isotherm). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Related Products of 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary