Li, Peiyu; Dong, Xiaoyun; Zhang, Ya; Lang, Xianjun; Wang, Cheng published the artcile< An azine-linked 2D porphyrinic covalent organic framework for red light photocatalytic oxidative coupling of amines>, Related Products of 3959-07-7, the main research area is azine porphyrinic covalent organic framework benzylamine photocatalytic oxidative coupling.
The construction of two-dimensional covalent organic frameworks (2D COFs) with robust stability for photocatalysis has gained intensive attention recently. Herein, we report the design and synthesis of a highly crystalline azine-linked porphyrinic 2D COF (Por-HZ-COF). Our results clearly show that Por-HZ-COF adopts an eclipsed AA stacking structure with a high Brunauer-Emmett-Teller (BET) sp. surface area of 1586 m2/g. In addition, Por-HZ-COF is chem. stable under various conditions, even in 12 M sodium hydroxide aqueous solution or 9 M hydrochloric acid. Moreover, Por-HZ-COF can be used for the photocatalytic aerobic oxidative coupling of benzylamines under red light irradiation with high activity and good reusability. This study demonstrates a novel robust 2D COF with azine linkage that has promising applications in photocatalysis.
Materials Today Chemistry published new progress about Anaerobic oxidation. 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Related Products of 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary