Lambright, Alison L.; Liu, Yanyao; Joyner, Isaac A.; Logan, Kaitlyn M.; Brown, M. Kevin published the artcile< Mechanism-Based Design of an Amide-Directed Ni-Catalyzed Arylboration of Cyclopentene Derivatives>, Product Details of C12H16BrNO2, the main research area is borylated cyclopentane amide derivative preparation; crystal structure borylated cyclopentane amide derivative; mol structure borylated cyclopentane amide derivative; amide directed nickel catalyzed diastereoselective arylboration cyclopentene derivative.
A method for amide-directed Ni-catalyzed diastereoselective arylboration of cyclopentenes is disclosed. The reaction allows for the synthesis of sterically congested cyclopentane scaffolds that contain an easily derivatized boronic ester and amide functional handles. The nature of the amide directing group and its influence on the reaction outcome were studied and ultimately reflect a predictably selective reaction based on the solvent and base counterion.
Organic Letters published new progress about Amides Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation) (borylated cyclopentene derivatives). 639520-70-0 belongs to class bromides-buliding-blocks, and the molecular formula is C12H16BrNO2, Product Details of C12H16BrNO2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary