Hu, Penghui; Tan, Mingxi; Cheng, Lu; Zhao, Hongyuan; Feng, Rui; Gu, Wei-Jin; Han, Wei published the artcile< Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes>, HPLC of Formula: 188813-04-9, the main research area is alkylarene polymethylhydrosiloxane promoter iron catalyst selective aerobic oxidation; aryl carbonyl compound preparation.
A bio-inspired iron-catalyzed polymethylhydrosiloxane-promoted aerobic oxidation of methylarenes to arylaldehydes with high yields and selectivities was reported. Notably, this method can tolerate oxidation-labile and reactive boronic acid group, which is normally required to be transformed immediately after its introduction and represents a significant advance in the area of the chem. of organoboronic acids, including the ability to incorporate both aldehyde and ketone functionalities into unprotected arylboronic acids, a class that can be difficult to access by current means. The robustness of this protocol was demonstrated on the late-stage oxidation of complex bioactive mols., including dehydroabietic acid, Gemfibrozil, Tocopherol nicotinate, a complex polyol structure and structurally complex arylboronic acids.
Nature Communications published new progress about Air. 188813-04-9 belongs to class bromides-buliding-blocks, and the molecular formula is C8H7BrO, HPLC of Formula: 188813-04-9.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary